Amadori

Rearengement of N-arylglycosylamines into 1-amino-1-deoxyketose.

Heyns reaction - With use of ammonia or RNH₂, a retro-rearengement can occur and the product will be 2-amino-2-deoxyaldose.

Bibliography

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• Heyns K., Meinecke K. H., Chem. Ber., 1953, 86, 1453.
• Michell F., Dijong J., Tetrahedron Letters, 1962, 21.
• Heyns K., Beilfuss W., Chem. Ber., 1973, 106, No.8, 2680-2692, 2693-2079.
• Vigdorchik M. M., JOH, 1974, 10, No.6, 1256-1262.
• Hodge J. E., Adv. in Carbohydrate Chem., 1955, 10, 165.