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Reaction Index
Dieckmann
Intramolecular condensation of complex esters to cyclic beta-ketoesters.
Dieckmann-Komppa synthesis - condensation of oxalic acid esters with esters of glutamic acid, followed by cyclization to produce alpha-diketones.
House-Babad method - synthesis of cyclic ketones by cyclization of phosphonium salts.
Bibliography
- Dieckmann W., Ber., 1894, 27, 102, 965; 1900, 33, 595, 2670; Ann., 1901, 317, 51, 93.
- House H. O., Babad H., J. Org. Chem., 1963, 28, 90.
- Thaoker M. R., Bagavant G., J. Ind. Chem. Soc., 1968, 45, 885.
- Chakravarti R. N., Dutta N., J. Ind. Chem. Soc., 1974, 51, 239-255.
- OR, 1, 345; OR, 15, 1.
Created by Bogdan Bogdanov , Zoran Zdravkovski and Kiril Hristovski
May 13, 1998; last updated XXXX XX, XXXX
« Institute of Chemistry, Skopje, Macedonia
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